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Preprint in the OpenAI Math release

A Coulomb ground-state density without Kohn-Sham ensemble representation

OpenAI

Abstract

We construct a finite three-electron Coulomb molecule whose spin-summed ground-state density cannot be reproduced by any ground-state ensemble of noninteracting electrons in a single real, spin-independent local potential in . The molecule has two equal positive integer nuclear charges, specified by an exact finite nonnumerical formula.

open until 1 Jan 2028

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